Polar-Solvent Effect on the Photocycloisomerization of Symmetrical Bis[anthracenes]: A Transient Ultrafast Kinetic Study

2001 ◽  
Vol 84 (9) ◽  
pp. 2520 ◽  
Author(s):  
Alexander S. Dvornikov ◽  
Jean-Pierre Desvergne ◽  
Dmitri A. Oulianov ◽  
Henri Bouas-Laurent ◽  
Peter M. Rentzepis
Keyword(s):  
Solvent Effect ◽  
Kinetic Study ◽  
Polar Solvent

scholarly journals Electroresponsive structuring and friction of a non-halogenated ionic liquid in a polar solvent: effect of concentration

2020 ◽  
Vol 22 (34) ◽  
pp. 19162-19171 ◽  
Author(s):  
Georgia A. Pilkington ◽  
Anna Oleshkevych ◽  
Patricia Pedraz ◽  
Seiya Watanabe ◽  
Milad Radiom ◽  
...  
Keyword(s):  
Atomic Force Microscopy ◽  
Ionic Liquid ◽  
Solvent Effect ◽  
Polar Solvent ◽  
Neutron Reflectivity ◽  
Force Microscopy ◽  
Frictional Properties ◽  
Atomic Force

Neutron reflectivity and atomic force microscopy results reveal the electroresponsive interfacial structuring and nano-frictional properties of ionic liquid (IL) lubricant mixtures with a polar solvent are strongly dependent on bulk IL concentration.

A Quantitative Investigation of the Ozonolysis Reaction. XVIII. A Kinetic Study of the Ozone Attack on Phenylethylenes

1973 ◽  
Vol 51 (20) ◽  
pp. 3398-3402 ◽  
Author(s):  
H. Henry ◽  
M. Zador ◽  
S. Fliszár
Keyword(s):  
Liquid Phase ◽  
Solvent Effect ◽  
Kinetic Study ◽  
Temperature Effect ◽  
Reaction Rates ◽  
Quantitative Investigation ◽  
Polar Solvents ◽  
Absolute Reaction

Absolute reaction rates for the ozonolysis of phenylethylenes in the liquid phase indicate: (i) a Hammett dependence, with [Formula: see text], for the ring-substituted trans stilbenes, (ii) a solvent effect, whereby the ozone attack is promoted by polar solvents, and (iii) no temperature effect between 15 and 35 °C, thus indicating [Formula: see text].

A Comparative Mechanistic and Kinetic Study of the Synthesis Reaction of 3, 4, 5-Substituted Furan-2(5H)-ones: Solvent Effect

2016 ◽  
Vol 1 (19) ◽  
pp. 6069-6078 ◽  
Author(s):  
Sayyed Mostafa Habibi-Khorassani ◽  
Mehdi Shahraki ◽  
Maryam Dehdab
Keyword(s):  
Solvent Effect ◽  
Kinetic Study ◽  
Synthesis Reaction

The polar solvent effect of transparent conductive films composed of graphene/PEDOT:PSS nanohybrids

2016 ◽  
Vol 303 ◽  
pp. 244-249 ◽  
Author(s):  
Che-Chun Liu ◽  
Ting-Yu Liu ◽  
Kuan-Syun Wang ◽  
Hui-Ming Tsou ◽  
Shih-Hsuan Wang ◽  
...  
Keyword(s):  
Solvent Effect ◽  
Polar Solvent ◽  
Transparent Conductive Films ◽  
Conductive Films

scholarly journals γ-valerolactone (GVL) as a bio-based green solvent and ligand for iron-mediated AGET ATRP

e-Polymers ◽  
2019 ◽  
Vol 19 (1) ◽  
pp. 323-329 ◽  
Author(s):  
XianRong Shen ◽  
DengZhou Xia ◽  
YiXin Xiang ◽  
JianGang Gao
Keyword(s):  
Molecular Weight ◽  
Kinetic Study ◽  
Polar Solvent ◽  
Monomer Conversion ◽  
Green Solvent ◽  
Polymer Molecular Weight ◽  
Aget Atrp ◽  
Halide Complexes

AbstractIn this paper, γ-valerolactone (GVL), a bio-based polar solvent, was applied as green solvent for iron(III)-catalyzed AGET ATRP without any external ligand. GVL is a fully degradable, non-toxic green solvent and has complex ability to iron halide complexes through –OCO- group. GVL as the solvent and the ligand for AGET ATRP of MMA in a controlled manner, as proved by kinetic study, the low PDI values and the increase in polymer molecular weight versus monomer conversion. Chain re-initiation experiments and 1HNMR characterization were conducted to further confirm the living feature.

Theoretical Studies on the Tautomeric Properties of Diamino-5-formamidopyrimidines

1998 ◽  
Vol 53 (11-12) ◽  
pp. 1027-1036 ◽  
Author(s):  
Piotr Cysewski
Keyword(s):  
Solvent Effect ◽  
Polar Solvent ◽  
Water Environment ◽  
Geometric Parameters ◽  
Stable Structure ◽  
Atomic Charges ◽  
Theoretical Studies

Abstract The results of theoretical geometry prediction of formamidopyrimidine(fapy)-adenine and fapy-guanine tautomers are presented. Among 54 potential tautomeric structures of fapy-adenine the most stable structure corresponds to the diamino-keto isomer. The solvent effect has insignificant influence on the fapy-adenine tautomers succession. The fapy-guanine has 172 potential isomers. There are three most stable tautomers of this guanine derivative, which may exchange the order depending on the polarity of the environment. In vapour the most probable is the 4-enol-6-keto-diamino tautomer, while in water environment the 4,6-diketo-diamino isomer is dominant. A more polar solvent stabilises more polar fapy-guanine tauto­mers. The geometric parameters and point-atomic charges corresponding to most probable tau­tomers are also supplied.

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